Pirólise catalítica da casca de café: estudo preliminar do rendimento líquido em diferentes condições operacionais

Authors

DOI:

https://doi.org/10.21712/lajer.2025.v12.n3.p188-194

Keywords:

desoxigenação catalítica, biomassa lignocelulósica, conversão termoquimica, bioenergia sustentável, melhoramento catalítico

Abstract

Resíduos agroindustriais lignocelulósicos, como a casca de café, apresentam potencial para a produção de biocombustíveis via pirólise catalítica. Este estudo teve como objetivo caracterizar essa biomassa e avaliar o rendimento líquido da pirólise catalítica in situ em reator de leito fixo. A casca de café foi submetida a análises físico-químicas e termogravimétricas. Os ensaios foram realizados em reator tubular sob atmosfera inerte de nitrogênio, com duas concentrações de catalisador (3% e 17%) e duas temperaturas (480°C e 640°C). A biomassa apresentou baixo teor de umidade e elevado teor de voláteis, indicando bom potencial energético. A maior produção de líquido (49%) foi obtida a 480°C com 17% de catalisador, enquanto a 640°C, a concentração de 3% resultou em rendimento superior (45%), provavelmente devido à intensificação de reações secundárias em temperaturas mais elevadas.

Downloads

Download data is not yet available.

Author Biographies

  • Talita Alves de Carvalho Tones, UFES CEUNES

    Environmental and Sanitary Engineer, graduated from the University Center of Caratinga (2013). Holds postgraduate degrees in Occupational Safety Engineering, Environmental Management from the Federal Institute of Espírito Santo (IFES), and Sanitation from Faveni. Currently pursuing a Master’s degree in Energy at the Federal University of Espírito Santo (UFES).

  • Andressa Alves da Silva, UFES CEUNES

    Estudante (Departamento de Engenharia e Tecnologia)

  • Érica Victor de Faria, UFES CEUNES

    Doutora em Engenharia Química pela Universidade Federal de Uberlândia (2022), atuando na área de sistemas particulados. Possui graduação em Engenharia Química pela Universidade Federal do Triângulo Mineiro (2015) e mestrado em Engenharia Química pela Universidade Federal de Uberlândia (2017). Tem experiência na área de Engenharia Química, com ênfase em Fenômenos de Transporte, Sistemas Particulados, Operações de Separação e Mistura, Pesquisa Operacional, Programação, Modelagem e Simulação, CFD. 

  • Thiago Padovani Xavier, UFES CEUNES
    Holds a PhD in Chemical Engineering from the Federal University of Uberlândia (2016), a Master's degree in Chemical Engineering from the Federal University of Uberlândia (2011), and a Bachelor's degree in Chemistry from the Federal University of Uberlândia (2003). Currently, he is an Adjunct Professor in the Department of Engineering and Technology at the Federal University of Espírito Santo, a position he has held since 2012, working on engineering-related topics concerning technological research and personnel training in the area of ​​management.
  • Vinícius Barroso Soares, UFES CEUNES

    Holds a degree in Chemical Engineering from the Federal Rural University of Rio de Janeiro (UFRRJ/2008), a master's degree in Chemical Engineering from the Federal Rural University of Rio de Janeiro (UFRRJ/2010), and a doctorate in Chemical Engineering from the Alberto Luiz Coimbra Institute for Graduate Studies and Research in Engineering (COPPE/2016). Currently, he is a professor in the Department of Engineering and Technology at the Federal University of Espírito Santo (UFES/present). He has professional experience in industry in the area of ​​process modeling, simulation, control, optimization, and safety, with an emphasis on risk management.

  • Taísa Shimosakai de Lira, UFES CEUNES

    She holds a Bachelor's degree in Chemical Engineering from the Federal University of Uberlândia (2003), a Master's degree in Chemical Engineering from the Federal University of Uberlândia (2005), and a Doctorate in Chemical Engineering from the Federal University of Uberlândia (2009). She is an Adjunct Professor in the Department of Engineering and Technology and a Permanent Professor in the Postgraduate Program in Energy, both at the Federal University of Espírito Santo. She has experience in the field of Chemical Engineering, with an emphasis on Modeling, Simulation and Optimization of Processes, mainly working with biomass pyrolysis. She is a Capixaba Researcher Fellow (FAPES Notice No. 06/2021) in the Pq - Research Productivity modality.

References

Basu, P (2010) Biomass gasification and pyrolysis: practical design and theory. Academic Press.

Bridgwater, AV (2012) ‘Review of fast pyrolysis of biomass and product upgrading,’ Biomass and Bioenergy, 38, pp. 68–94. https://doi.org/10.1016/j.biombioe.2011.01.048

Chan, YH, Dang, KV, Yusup, S, Lim, MT, Zain, AM and Uemura, Y (2014) ‘Studies on catalytic pyrolysis of empty fruit bunch (EFB) using Taguchi’s L9 Orthogonal Array,’ Journal of the Energy Institute, 87(3), pp. 227–234. https://doi.org/10.1016/j.joei.2014.03.008

David, GF et al. (2021) ‘Fast pyrolysis as a tool for obtaining levoglucosan after pretreatment of biomass with niobium catalysts,’ Waste Management, 126, pp. 274–282. https://doi.org/10.1016/j.wasman.2021.03.016

Dias, S de A, Toscano Miranda, N, Maciel Filho, R, Sphaier, LA and Castillo Santiago, Y (2025) ‘Sugarcane Bagasse Fast Pyrolysis: Pilot Plant Challenges,’ Processes, 13(7). https://doi.org/10.3390/pr13072116

Dechao, W et al. (2025) ‘Ex-situ combined with in-situ catalytic pyrolysis: A strategic approach to enhancing furans production from biomass,’ Renewable Energy, 244. https://doi.org/10.1016/j.renene.2025.122697

El Bari, H et al. (2024) ‘Catalytic fast pyrolysis of lignocellulosic biomass: Recent advances and comprehensive overview,’ Journal of Analytical and Applied Pyrolysis. Elsevier B.V. https://doi.org/10.1016/j.jaap.2024.106390

El-Sayed, SA, Khass, TM and Mostafa, ME (2024) ‘Thermal degradation behaviour and chemical kinetic characteristics of biomass pyrolysis using TG/DTG/DTA techniques,’ Biomass Conversion and Biorefinery, 14(15), pp. 17779–17803. https://doi.org/10.1007/s13399-023-03926-2

Gupta, R et al. (2025) ‘Sustainable valorization of bamboo sawdust via catalytic pyrolysis into renewable liquid fuel and value-added chemicals,’ Engineering Research Express, 7(1). https://doi.org/10.1088/2631-8695/adc0e8

Hassan, NS, Jalil, AA, Hitam, CNC, Vo, DVN and Nabgan, W (2020) ‘Biofuels and renewable chemicals production by catalytic pyrolysis of cellulose: a review,’ Environmental Chemistry Letters. Springer Science and Business Media Deutschland GmbH, pp. 1625–1648. https://doi.org/10.1007/s10311-020-01040-7

Hematkhah, R, Majidian, N, Hallajisani, A and Samipoorgiri, M (2023) ‘Investigation of catalytic pyrolysis of spirulina for bio-oil production,’ Arabian Journal of Chemistry, 16(5). https://doi.org/10.1016/j.arabjc.2023.104691

Kumar Mishra, R (2022) ‘Pyrolysis of low-value waste switchgrass: Physicochemical characterization, kinetic investigation, and online characterization of hot pyrolysis vapours,’ Bioresource Technology, 347. https://doi.org/10.1016/j.biortech.2022.126720

Rehan, M et al. (2017) ‘Effect of zeolite catalysts on pyrolysis liquid oil,’ International Biodeterioration and Biodegradation, 119, pp. 162–175. https://doi.org/10.1016/j.ibiod.2016.11.015

Sánchez-Borrego, FJ, Álvarez-Mateos, P and García-Martín, JF (2021) ‘Biodiesel and other value-added products from bio-oil obtained from agrifood waste,’ Processes, 9(5). https://doi.org/10.3390/pr9050797

Setter, C et al. (2020) ‘Slow pyrolysis of coffee husk briquettes: Characterization of the solid and liquid fractions,’ Fuel, 261. https://doi.org/10.1016/j.fuel.2019.116420

Shafaghat, H et al. (2019) ‘In-situ and ex-situ catalytic pyrolysis/co-pyrolysis of empty fruit bunches using mesostructured aluminosilicate catalysts,’ Chemical Engineering Journal, 366, pp. 330–338. https://doi.org/10.1016/j.cej.2019.02.055

Shakor, ZM, Tayib, YM, AbdulRazak, AA, Shnain, ZY and Al-Shafei, E (2025) ‘Thermogravimetric Analysis Integrated with Mathematcal Methods and Artificial Neural Networks for Optimal Kinetic Modeling of Biomass Pyrolysis: A Review,’ ACS Omega. American Chemical Society, pp. 36750–36770. https://doi.org/10.1021/acsomega.5c02250

Sheng, C and Azevedo, JLT (2005) ‘Estimating the higher heating value of biomass fuels from basic analysis data,’ Biomass and Bioenergy, 28(5), pp. 499–507. https://doi.org/10.1016/j.biombioe.2004.11.008

Tang, X et al. (2024) ‘In-situ and ex-situ selective catalysis of biochar-based catalysts for the production of high-quality bio-oil and H2-rich gas from tobacco stem,’ Journal of Environmental Chemical Engineering, 12(6). https://doi.org/10.1016/j.jece.2024.114268

Tian, B, Xu, L, Jing, M, Liu, N and Tian, Y (2021) ‘A comprehensive evaluation on pyrolysis behavior, kinetics, and primary volatile formation pathways of rice husk for application to catalytic valorization,’ Fuel Processing Technology, 214. https://doi.org/10.1016/j.fuproc.2020.106715

Wang, S, Persson, H, Yang, W and Jönsson, PG (2018) ‘Effect of H2 as Pyrolytic Agent on the Product Distribution during Catalytic Fast Pyrolysis of Biomass Using Zeolites,’ Energy and Fuels, 32(8), pp. 8530–8536. https://doi.org/10.1021/acs.energyfuels.8b01779

Xu, X, Chen, S, Wang, Y, Lv, P, Guo, W and Shu, Y (2025) ‘Investigation of the temperature influence on the catalytic hydrogenation upgrading of bio-oil using industrial nickel based catalyst RZ409,’ Scientific Reports, 15(1). https://doi.org/10.1038/s41598-025-14087-9

Yang, H, Yan, R, Chen, H, Lee, DH and Zheng, C (2007) ‘Characteristics of hemicellulose, cellulose and lignin pyrolysis,’ Fuel, 86(12–13), pp. 1781–1788. https://doi.org/10.1016/j.fuel.2006.12.013

Published

11/29/2025

Issue

Section

Eficiência Energética

How to Cite

Alves de Carvalho Tones, T. (2025) “Pirólise catalítica da casca de café: estudo preliminar do rendimento líquido em diferentes condições operacionais”, Latin American Journal of Energy Research, 12(3), pp. 188–194. doi:10.21712/lajer.2025.v12.n3.p188-194.

Similar Articles

1-10 of 63

You may also start an advanced similarity search for this article.